Brad Pitt and Angelina Jolie have previously confessed that they fell in love on the sets of "Mr. and Mrs. Smith" in 2004 when the actor was still married to Jennifer Aniston, though Pitt insists that they did not start dating until his separation from the "Friends" alum.A recent report in The Mirror claims that Brad Pitt and Angelina Jolie connected at an intimate barbecue thrown by the actress a month after the filming started in January, adding that their chemistry was obvious to everyone on the set.Sources from the set claim that the 45-year-old actress "huddled close" to her co-star during the get-together at her mansion in Brentwood, Los Angeles.
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